In a pack of CaCl2 and H2O, hydrolysis of Ca+2 will occur
This will result in formation of Ca(OH)2.
The reaction is exothermic in nature
so the balanced thermo-chemical equation will be
CaCl2(aq) + H2O (l) ---> Ca(OH)2 + 2HCl + Heat
In a pack of NH4NO3 and H2O hydrolysis of NH4+ will occur as
NH4NO3 (aq) + H2O(l) + Heat ---> NH4OH(aq) + HNO3 (aq)
It is an endothermic reaction
